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11.
Ho Van Doanh Phan Bao Quoc Hieu Pham Ngoc Son Dao Van Hoang Tam Hoang Duc Ho Manh Dung 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(3):1361-1365
Journal of Radioanalytical and Nuclear Chemistry - To keep the accredited category for the gamma spectrometry test in our laboratory, the efficiency curves of a HPGe detector for soil sample in... 相似文献
12.
Mihály V. Pilipecz Tamás R. Varga Péter Králl Zoltán Vincze Zoltán Mucsi Ruth Deme 《合成通讯》2020,50(11):1712-1723
AbstractThe novel push–pull alkene, the 2-(nitro-nitrosomethylene)-pyrrolidine with numerous aliphatic or aromatic amines as nucleophiles afforded amidoximes. Various substituted oxadiazaborole and oxadiazole derivatives were prepared starting from these amidoximes, widening the synthetic applicability of the push–pull alkenes. Acylation of the amidoximes was also examined. The mechanism of the amidoxime formation was investigated by computational methods. 相似文献
13.
Aragón Artacho Francisco J. Campoy Rubén Tam Matthew K. 《Computational Optimization and Applications》2021,80(2):549-585
Computational Optimization and Applications - In this work, we develop a systematic framework for computing the resolvent of the sum of two or more monotone operators which only activates each... 相似文献
14.
Structural Characterization of O‐ and C‐Glycosylating Variants of the Landomycin Glycosyltransferase LanGT2 下载免费PDF全文
Dr. Heng Keat Tam Dr. Johannes Härle Dr. Stefan Gerhardt Prof. Dr. Jürgen Rohr Guojun Wang Prof. Dr. Jon S. Thorson Dr. Aurélien Bigot Monika Lutterbeck Dr. Wolfgang Seiche Prof. Dr. Bernhard Breit Prof. Dr. Andreas Bechthold Prof. Dr. Oliver Einsle 《Angewandte Chemie (International ed. in English)》2015,54(9):2811-2815
The structures of the O‐glycosyltransferase LanGT2 and the engineered, C? C bond‐forming variant LanGT2S8Ac show how the replacement of a single loop can change the functionality of the enzyme. Crystal structures of the enzymes in complex with a nonhydrolyzable nucleotide‐sugar analogue revealed that there is a conformational transition to create the binding sites for the aglycon substrate. This induced‐fit transition was explored by molecular docking experiments with various aglycon substrates. 相似文献
15.
Zsolt Zsótér Tibor Tímár Krisztina Kónya Tamás Patonay József Jekő 《Journal of heterocyclic chemistry》2015,52(6):1677-1683
4,4‐Dimethylchromeno[4,3‐d]selenadiazoles 8 with insecticide activities have been synthesized via oxidative ring closure of the corresponding semicarbazone derivatives 7 by treatment with selenium dioxide. Reaction of various alkoxy‐2,2‐dimethyl‐2H‐benzopyrans with phenylselenyl chloride was utilized to prepare different phenylselenyl‐ and 3‐chloro precocene analogs. 相似文献
16.
17.
Tam T. T. N. Nguyen Jesper Østergaard Bente Gammelgaard 《Analytical and bioanalytical chemistry》2015,407(28):8497-8503
18.
The primal-dual Dikin-type affine scaling method was originally proposed for linear optimization and then extended to semidefinite optimization. Here, the method is generalized to symmetric conic optimization using the notion of Euclidean Jordan algebras. The method starts with an interior feasible but not necessarily centered primal-dual solution, and it features both centering and reducing the duality gap simultaneously. The method’s iteration complexity bound is analogous to the semidefinite optimization case. Numerical experiments demonstrate that the method is viable and robust when compared to SeDuMi, MOSEK and SDPT3. 相似文献
19.
Solution sets of systems of linear equations over fields are characterized as being affine subspaces. But what can we say about the “shape” of the set of all solutions of other systems of equations? We study solution sets over arbitrary algebraic structures, and we give a necessary condition for a set of n-tuples to be the set of solutions of a system of equations in n unknowns over a given algebra. In the case of Boolean equations we obtain a complete characterization, and we also characterize solution sets of systems of Boolean functional equations. 相似文献
20.
Mahitha Udayakumar Bilal El Mrabate Tamás Koós Katalin Szemmelveisz Ferenc Kristály Máté Leskó Ádám Filep Róbert Géber Mateusz Schabikowski Péter Baumli János Lakatos Pál Tóth Zoltán Németh 《Arabian Journal of Chemistry》2021,14(7):103214
Carbon foams have gained significant attention due to their tuneable properties that enable a wide range of applications including catalysis, energy storage and wastewater treatment. Novel synthesis pathways enable novel applications via yielding complex, hierarchical material structure. In this work, activated carbon foams (ACFs) were produced from waste polyurethane elastomer templates using different synthesis pathways, including a novel one-step method. Uniquely, the produced foams exhibited complex structure and contained carbon microspheres. The ACFs were synthesized by impregnating the elastomers in an acidified sucrose solution followed by direct activation using CO2 at 1000 ℃. Different pyrolysis and activation conditions were investigated. The ACFs were characterized by a high specific surface area (SBET) of 2172 m2/g and an enhanced pore volume of 1.08 cm3/g. Computer tomography and morphological studies revealed an inhomogeneous porous structure and the presence of numerous carbon spheres of varying sizes embedded in the porous network of the three-dimensional carbon foam. X-ray diffraction (XRD) and Raman spectroscopy indicated that the obtained carbon foam was amorphous and of turbostratic structure. Moreover, the activation process enhanced the surface of the carbon foam, making it more hydrophilic via altering pore size distribution and introducing oxygen functional groups. In equilibrium, the adsorption of methylene blue on ACF followed the Langmuir isotherm model with a maximum adsorption capacity of 592 mg/g. Based on these results, the produced ACFs have potential applications as adsorbents, catalyst support and electrode material in energy storage systems. 相似文献